Charles-Edouard Guillaume The Nobel Prize in Physics 1920

biography

Charles-Edouard Guillaume was born in Fleurier, Switzerland, on February 15, 1861. Guillaume received his high school education at the Neuch?tel gymnasium. At the age of 17, he enrolled in the Zurich Polytechnic (later the Federal Institute of Technology). He rapidly developed an interest in physics, later claiming that Fran?ois Arago's text, ?loges acad?miques, was particularly influential on his decision to pursue science as a career. Guillaume was awarded a Ph.D. in 1882 for his thesis on electrolytic capacitors.

Guillaume spent his compulsory year of military service as an artillery officer, during which time he studied mechanics and ballistics. He was then offered a position with the newly created International Bureau of Weights and Measures in S?vres, France, just outside Paris. He worked there over the next half century, becoming associate director of the bureau in 1902, director in 1905, and finally honorary director upon his retirement in 1936. Guillaume's earliest work at the bureau was in the establishment, duplication, and distribution of international standards. That work included the most fundamental metrological operations, such as calibrating thermometers and making precise copies of the standard meter for distribution to countries around the world.

It was the latter task that resulted in an accidental discovery for which Guillaume is perhaps best known. The standard meter bar kept at the bureau in S?vres had been made of a platinum-iridium alloy to prevent corrosion and other changes.

Making dozens of copies of this bar from such costly metals was, however, prohibitively expensive. As a result, Guillaume began to look for other materials from which to make duplicates of the standard meter bar. One of the alloys Guillaume prepared consisted of about seven parts iron to three parts nickel. In working with this alloy, he found that it had an extremely low coefficient of expansion. He decided to undertake a systematic study of other iron-nickel alloys and eventually found one whose coefficient of expansion was zero. This alloy, containing about 36% nickel and 64% iron, was later named invar. The value of invar in metrology is obvious. Measuring devices made of the alloy will not change in size at all as a result of changes in temperature. But invar soon found applications in many other fields. For example, it became invaluable in clockmaking, as did a second alloy invented by Guillaume called elinvar. The watch part called the balance, if it contained one of these two alloys, eventually became known as a "Guillaume balance."

In addition to the Nobel Prize he was awarded in 1920, Guillaume received a number of other honors during his lifetime, including selection as a grand officer of the Legion of Honor, election as president of the French Physical Society, and receipt of honorary degrees from the universities of Geneva, Neuch?tel, and Paris. Guillaume was married in 1888 to A. M. Taufflich; they had three children. Guillaume died at S?vres on June 13, 1938.

Charles-Edouard Guillaume was born at Fleurier, in the Swiss-Jura, on February 15, 1861. His grandfather had left France for political reasons during the Revolution and established a watchmaking business in London. The business was carried on by his three sons but Charles' father, ?douard, eventually returned to settle in Fleurier. Guillaume received his early education in Neuch?tel before going to the Zurich Polytechnic where he obtained his doctor's degree. He spent a short time as an officer in the artillery before entering the International Bureau of Weights and Measures, as an assistant, in 1883. He became Associate Director in 1902 and from 1915 until his retirement in 1936, he was Director of the Bureau. He remained as Honorary Director from 1936 until his death.

During his brief military career, Guillaume studied mechanics and ballistics but his earliest investigations at the bureau were with thermometry. He carried out important investigations on corrections to mercury-in-glass thermometers and he was responsible for the detailed calibration of thermometers used at the Bureau in the establishment of the thermal expansions of the standards of length. He was concerned in initial work on the International Metre and undertook a determination of the volume of one kilogram of water by the contact method.

A chance observation by Guillaume on the coefficient of expansion of nickel-iron alloys led to a systematic investigation of a whole series of alloys and the discovery of invar, an alloy with a very low coefficient of expansion; elinvar, for which the thermoelastic coefficient is practically zero, i.e. Young's modulus constant, over a considerable temperature range; together with other useful alloys. The applications of invar were quickly recognized and the material was used in rapid methods for the measurement of geodetic baselines. The alloy is widely used in instruments of precision, such as thermostats and pendulums of astronomic clocks. Guillaume's total compensating balance for high-grade watches and chronometers, which eliminates the secondary error, was perfected by an elinvar hair spring. Guillaume's work is recorded in many papers published by the Bureau and he has written, amongst other works, ?tudes thermom?triques (Studies on Thermometry, 1886), Trait? de thermom?trie (Treatise on Thermometry, 1889), Unit?s et ?talons (Units and Standards, 1894), Les rayons X (X-Rays, 1896), Recherches sur le nickel et ses alliages (Investigations on Nickel and its Alloys, 1898), La vie de la mati?re (The Life of Matter, 1899), La Convention du M?tre et le Bureau international des Poids et Mesures (Metrical Convention and the International Bureau of Weights and Measures, 1902), Les applications des aciers au nickel (Applications of Nickel-Steels, 1904), Des ?tats de la mati?re (States of Matter, 1907), Les r?cent progr?s du syst?me m?trique (Recent progress in the Metric System, 1907, 1913). His book Initiation ? la M?canique (Introduction to Mechanics) has been translated into several languages.

He was appointed Grand Officer of the Legion of Honour and received honorary Doctor of Science degrees from the Universities of Geneva, Neuchatel and Paris. He was a President of the Soci?t? Fran?aise de Physique and a member, honorary member or corresponding member of more than a dozen of the leading scientific academies of Europe. Charles-?douard Guillaume married Mlle. A.M. Taufflieb in 1888. They had three children. He died on May 13, 1938.

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